Module 2.5 General Chemistry 1 w Lab

Objectives

  • Explain and apply observed trends in atomic size, ionization energy, and electron affinity of the elements

Periodic Variations in Element Properties

  • Why do elements in periodic table exhibit similar chemical behavior?
    • Because members of a group have the same number and distribution of e- in their valence shells
      • A period is a horizontal row of the periodic table. A group is a vertical row of the periodic table
      • Even though valence electrons stay the same, the principle quantum number increases by one
  • What are other patterns in the periodic table?
    • Moving down a group
      • Metallic character of atoms increases
      • Elements become more solid
    • Left to right
      • Add proton to nucleus + electron to valence shell
  • What 3 properties vary periodically as electron structures and elements change
    • Size
    • Ionization E
    • Electron affinities

Variation in Covalent Radius

  • How to determine relative size of an atom?
    • Covalent radius
      • Defined as half distance between nuclei of 2 identical atoms joined by covalent bond
  • What happens when the principle quantum number increases by one for each element?
    • electrons are being added to a region of space increasingly distant from the nucleus
    • Atom size and covalent radius must increase as we increase distance of outermost electrons from the nucleus IMG_8144.jpeg

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Terminology